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Nd:YVO4

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我司的Nd:YVO4晶體產品,又稱摻釹釩酸釔晶體。是一種綜合性能出色的制作半導體泵浦固體激光器的激光晶體產品。Nd:YVO4晶體廣泛用于在機械、材料加工、波譜學、晶片檢驗、顯示器、醫學檢測、激光印刷、數據存儲等多個領域。該產品有熱導性能好,受激發射截面大,激光損傷閾值高、吸收帶寬,吸收峰約808nm等特點。由于這些優點,小晶體可以用來制造更小的激光器件。Nd:YVO4晶體的另一個特點是它是單軸的,這使得它發出線性偏振光。與倍頻晶體相結合,可以實現綠、藍、紅三種波長的全固態激光器。現在Nd:YVO4激光器已在機械、材料加工、波譜學、晶片檢驗、顯示器、醫學檢測、激光印刷、數據存儲等多個領域得到廣泛的應用。而且Nd:YVO4二極管泵浦固態激光器正在迅速取代傳統的水冷離子激光器和燈泵浦激光器的市場,尤其是在小型化和單縱模輸出方面。可以運用在激光二極管泵浦全固態(DPSS)微小型激光器,激光雷達,遙感衛星產品之中。

特點

  • 吸收系數高
  • 受激發射截面大
  • 吸收帶寬
  • 損傷閾值高
  • 單軸晶體
  • 良好的物理和光學性能

材料規格

材料Nd: YVO4
濃度公差(atm%)0.5%, 1.1%, 2.0%, 3.0%
取向A-cut or C-cut
平行性20〞
垂直性5〞
表面質量符合MIL-O-13830 B10/5劃痕/凹陷
波前畸變<λ/8 @633nm
表面平整度λ/10@ 633 nm
通光孔徑>90%
倒角≤0.2mm@450
尺寸公差(W±0.1mm)x(H±0.1mm)x(L+0.2/-0.1mm) (L<2.5mm)
(W±0.1mm)x(H±0.1mm)x(L+0.5/-0.1mm) (L≥2.5mm)
角度公差≤0.5°
損傷閾值[GW / cm2]>1 for 1064nm, TEM00, 10ns, 10Hz (AR-涂層)
涂層HR@1064nm+532nm+HT@808nm/AR@1064nm+532nm

物理和化學特性

晶體結構鋯石四方體,空間群D4h-I4 / amd
晶格常數a=b=7.12, c=6.29
密度4.22g/cm3
熔點1825
導熱系數/(W·m-1·K-1 @ 25°C)5.2
熱光學系數(dn / dT)dno/dT=8.5×10-6/K; dne/dT=2.9×10-6/K
熱膨脹率/(10-6·K-1 @ 25°C)a = 4.43, c= 11.4
硬度(莫氏)4~5

光學和光譜性質

激光波長1064nm, 1342nm
偏振激光發射π偏振;平行于光軸(c軸)
泵浦波長808nm
本征損失0.02cm-1?@1064nm
二極管泵浦光到光效率>60%
發射截面25×10-19cm2@1064nm
熒光壽命90 μs (大約 50 μs for 2 atm% Nd 摻雜) @ 808 nm
增益帶寬0.96nm @1064nm
折光率1.9573(no); 2.1652(ne) @1064nm
1.9721(no); 2.1858(ne) @808nm
2.0210(no); 2.2560(ne) @532nm
吸收系數31.4 cm-1?@ 808 nm
吸收長度0.32 mm @ 808 nm
增益帶寬0.96 nm (257 GHz) @ 1064 nm

吸收和發射光譜

Nd-YVO4激光晶體-吸收譜1-南京光寶-CRYLINKNd-YVO4激光晶體-吸收譜2-南京光寶-CRYLINK
Nd-YVO4激光晶體-發射譜π-南京光寶-CRYLINKNd-YVO4激光晶體-發射譜σ-南京光寶-CRYLINK

參考文獻

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[2] Dal, Hoy, Kwon, et al. Growth of Nd-doped YVO4 single crystals along 〈1?0?0〉tetra by the anisotropic heating floating zone method[J]. Journal of Crystal Growth, 2009.
[3]? Lin H Y ,? Copner N ,? Sun D , et al. Dual-wavelength CW a-cut Nd:YVO4 laser at 1064.3 and 1066.7nm[J]. OPTIK -STUTTGART-, 2016.
[4]? Lin H Y ,? Sun D ,? Huang X H , et al. Continuous-wave dual-wavelength Nd:YVO4 laser at 1066.4nm and 1083.8nm[J]. Optik – International Journal for Light and Electron Optics, 2016, 127(11):4824-4825.
[5]? Zhuang Z ,? Tao L ,? Li X , et al. Investigation of Nd:YVO4/YVO4 composite crystal and its laser performance pumped by a fiber coupled diode laser[J]. Optics Communications, 2007, 274(1):176-181.
[6] H.F. Lin and W.Z. Zhu and F.B. Xiong and R.Z. Mu and Y.Q. Huang. A high polarization microchip green laser with dual Nd:YVO4 crystal[J]. Optics & Laser Technology, 2012.
[7]? Zhang H ,? Liu J ,? Wang J , et al. Laser properties of different Nd-doped concentration Nd:YVO 4 laser crystals[J]. Optics & Lasers in Engineering, 2002, 38(6):527-536.
[8]? Li S ,? Li Y ,? Zhao S , et al. Thermal effect investigation and passively Q-switched laser performance of composite Nd:YVO4 crystals[J]. Optics & Laser Technology, 2015, 68:146-150.
[9]? Sugiyama A ,? Nara Y . Improved direct bonding method of Nd:YVO and YVO laser crystals[J]. Ceramics International, 2005, 31(8):1085-1090.
[10]? Meng X ,? Li Z ,? Zhang H . Growth, morphology and laser performance of Nd:YVO4 crystal[J]. Journal of Crystal Growth, 1999, 200(1/2):199-203.
[11]? Zhang H ,? Meng X ,? Li Z , et al. Growth, spectra and influence of annealing effect on laser properties of Nd:YVO 4 crystal[J]. Optical Materials, 2000, 14(1):25-30.
[12]? Lian Z ,? Peng L ,? Liu T , et al. Optical properties of planar waveguide in Nd:YVO4 crystal formed by swift Kr8+ ion irradiation[J]. Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms, 2013, 307(8):459-462.
[13]? Ma Y J , F Lu,? Yin J J , et al. Radiation damage study of MeV ions-implanted Nd:YVO4 crystal[J]. Materials Science and Engineering: B, 2013, 178(20):1464-1468.
[14] Alfred, R, Forbes, et al. The hydrothermal synthesis, solubility and crystal growth of YVO4 and Nd:YVO4[J]. Journal of Crystal Growth, 2008, 310(20):4472-4476.
[15]? Wang Z ,? Sun L ,? Zhang S , et al. Investigation of LD end-pumped Nd:YVO 4 crystals with various doping levels and lengths[J]. Optics & Laser Technology, 2001, 33(1):47-51.
[16]? G. V , Vázquez, and, et al. Analysis of ion implanted waveguides formed on Nd:YVO4 crystals – ScienceDirect[J]. Optics Communications, 2004, 240(4-6):351-355.
[17]? Huang C H ,? Chen J C . Nd : YVO4 single crystal fiber growth by the LHPG method[J]. Journal of Crystal Growth, 2001, 229:184–187.
[18]? Zhang H ,? Fang H S ,? Zheng L L , et al. Nd:YVO4 crystal growth by Czochralski technique with a submerged plate[J]. Journal of Crystal Growth, 2009, 311(22):4652-4659.
[19]? Shur J W ,? Kochurikhin V V ,? Borisova A E , et al. Photoluminescence properties of Nd:YVO 4 single crystals by multi-die EFG method[J]. Optical Materials, 2004, 26(4):347-350.
[20] S. Erdei and B.M. Jin and F.W. Ainger and B. Keszei and J. Vandlik and A. Süveges. Possible trends for the growth of low scattering Nd:YVO4 laser crystals; phase relations — growth techniques[J]. Journal of Crystal Growth, 1997.
[21]? Hu B Q ,? Zhang Y Z ,? Wu X , et al. Defects in large single crystals Nd : YVO 4[J]. Journal of Crystal Growth, 2001, 226(4):511-516.
[22]? Goutaudier C ,? Ermeneux F S ,? Cohen-Adad M T , et al. LHPG and FLUX growth of various Nd:YVO4 single crystals: A comparative characterization[J]. Materials Research Bulletin, 1998, 33(10):1457-1465.
[23] Hur,? M. G , Yang, et al. Optical properties of EFG grown Nd:YVO4 single crystals dependent on Nd concentration.[J]. Journal of Crystal Growth, 2002.
[24]? Nakamura K ,? Kasahara K ,? Sato M , et al. Interferometric studies on a diode-pumped Nd:YVO 4 laser with frequency-shifted feedback[J]. Optics Communications, 1995, 121(4-6):137-140.
[25]? Helen Y ,? Dassow R ,? Nerding M , et al. High mobility thin film transistors by Nd:YVO4-laser crystallization[J]. Thin Solid Films, 2001, 383(1-2):143-146.
[26]? Watanabe S ,? Nakamura O ,? Kochurikhin V V , et al. Growth of Nd:YVO 4 single-crystal plates by the edge-defined, film-fed growth technique[J]. Journal of Crystal Growth, 2007, 305(1):181-184.
[27] MD Wei,? Hsu C C . Numerical study of nonlinear dynamics in a pump-modulation Nd:YVO4 laser with humped modulation profile[J]. Optics Communications, 2012, 285(6):1366-1370.
[28]? Chen Y ,? Wu E ,? Zhang S , et al. A novel ring laser resonator of linear geometry with twin off-axially cut Nd:YVO4[J]. Optics Communications, 2003, 220(1-3):179-186.

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